Plasma-sprayed hydroxylapatite coatings, widely used on metallic surgical implants to improve their adhesion to bone, are formed by rapid quenching of molten, or partly molten, particles which impact the substrate at high velocity. the performance of these coatings in the body depends upon their structure, which is not well understood. Coatings prepared under a range of spraying conditions have been studied by X-ray diffraction (XRD). differential thermal analysis (DTA), thermogravimetric analysis (TGA) and solid-state nuclear magnetic resonance spectroscopy (NMR). The results suggest that particles partly melt and lose combined water at lower plasma torch input powers forming a glass, by quenching of the liquid phase, and an OH-depleted hydroxylapatite residual crystalline phase. At higher power inputs an increasing amount of P2O5 is also lost and the coatings contain CaO and Ca4P2O9. Heat treatment of coatings in air at 600°C results in crystallization of the glass phase and reaction with water vapour to form hydroxylapatite. The results show that XRD is relatively insensitive to some of the structural details of hydroxylapatite coatings which may be significant to their performance. NMR provides more structural information and is a significant tool for coating characterization.
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Sadly Professor McPherson died after completing this paper. He made a distinctive contribution to the fields of ceramics and thermal spraying and will be missed by the international community.
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McPherson, R., Gane, N. & Bastow, T.J. Structural characterization of plasma-sprayed hydroxylapatite coatings. J Mater Sci: Mater Med 6, 327–334 (1995). https://doi.org/10.1007/BF00120300
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DOI: https://doi.org/10.1007/BF00120300